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Citation: Li Guowen, Liang Yingqiu, Wu Lixin. Excitation Energy Transfer of Multiple Systems Mediated by Synthetic Bilayer Membrane Containing Biphenyl Moiety[J]. Chinese Journal of Applied Chemistry, ;1997, 14(5): 39-42. shu

Excitation Energy Transfer of Multiple Systems Mediated by Synthetic Bilayer Membrane Containing Biphenyl Moiety

1.
Institute of Theoretical Chemistry, Jilin University, Changchun 130023

Received Date: 4 December 1996
Available Online: 19 June 1997
Fund Project:

Ternary excitation energy transfer from biphenyl donor embeded in the interior of bilayer membranes cascading through membrane-bound titan yellow to membrane-bound rhodamine B was investigated in the mixture system of DBBTAB(4-(4'-decyloxybiphenyl-4-oxytrimethyl) ammonium bromide) vesicles. The energy transfer efficiency of the ternary system was good. The specific function of the DBBTAB vesicles in energy transfer was explored and the mechanism of energy transfer was discussed. Furthermore, the cascading energy transfer among biphenyl, titan yellow, fluorescein, rhodamine B and tetraphenyl porphin, which anchored on the surface of the DBBTAB membrane except biphenyl, was also observed in the same mixture system. It improved the light efficiency and extended the spectral region. The experiment results imply that DBBTAB vesicle is a promising efficient medium for energy transfer in dye lasers and a better membrane mimetic agent.
- bilayer membrane,
- vesicle,
- fluorescence,
- energy transfer
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