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Citation: Wang Xiaomei, Yang Ping, Cai Qinghua, Bao Meng. Solid Liquid Phase Transfer Catalytic Synthesis of Alkyl Phosphoric Dialkyl Ester andTheir Flame Retardancy[J]. Chinese Journal of Applied Chemistry, ;1997, 14(3): 96-98. shu

Solid Liquid Phase Transfer Catalytic Synthesis of Alkyl Phosphoric Dialkyl Ester andTheir Flame Retardancy

1.
Department of Applied Chemistry, Shandong Institute of Building Materials, Jinan 250022

Received Date: 12 August 1996
Available Online: 3 March 1997

Eight alkyl phosphoric dialkyl esters were synthesized by reacting potassium dialkyl phosphite with different halohydrocarbons in the presence of quaternary ammonium salt and KOH. Their structures were identified by IR and NMR. The mixtures of epoxy resin with phosphonates showed a better flame retardancy and plasticization than that with phosphates.
- alkyl phosphoric dialkyl ester,
- synthesis,
- phase transfer catalysis,
- flame retardancy
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