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Citation: Zhang Weihua, Xin Xinquan. The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio) Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature[J]. Chinese Journal of Applied Chemistry, ;1997, 14(3): 81-83. shu

The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio) Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature

Zhang Weihua ¹ ,
Xin Xinquan ²

1.
1. Department of Chemistry, Hubei Normal University, Huangshi 435002;
2.
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093

Received Date: 4 August 1996
Available Online: 11 March 1997
Fund Project:

The solid-solid state reaction of 2,2'-(p-phenylenedimethylenethio) diacetic acid with cobalt acetate tetrahydrate has been studied. XRD, IR, ESR, TG-DTA and elemental analysis were used to characterize the solid product. The kinetics of the isothermal solid state reaction was investigated by using the electrical conductivity measurement. The kinetics of this system conforms to a A₃ mechanism, the activation energy is calculated to be E_a=104.7 kJ/mol.
- p-phenylenedimethylenethio diacetic acid,
- cobalt acetate tetrahydrate,
- solid state reaction,
- kinetics
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