Citation: Lin Yanan, Zhang Chongrong, Dong Wenhao, Zhang Shuyong. Kinetics and Mechanism of Solution Reaction-2: Influential Factors and General Form of Kinetic Equation[J]. Chemistry, ;2016, 79(12): 1204-1208. shu

Kinetics and Mechanism of Solution Reaction-2: Influential Factors and General Form of Kinetic Equation

1.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100

Corresponding author: Zhang Shuyong,
Received Date: 25 April 2016
Available Online: 30 June 2016

The influential factors for the rate of reactions occurring in solution which is different from those occurring in gaseous phase are discussed. The perception that the presence of solvent molecules will cause a significant decrease in the collision frequency between reactant molecules is proved incorrect. Except for the changes in activity of reactants and the catalysis due to the presence of solvent, solvent effect and micro-viscosity are found to be the two main factors affecting the rate of the solution reactions. The micro-viscosity is either of positive value due to the interaction between reactants and solvent molecules or of negative value due to the small molar mass of solvent which moves with higher speed. Based on the simple collision theory and transition state theory, a general kinetic equation correlating the change in reaction rate to the change in activation energy and micro-viscosity is proposed. Base on this equation, more satisfactory explanations to the experimental facts can be given.
- Solution reaction,
- Solvent effect,
- Micro-viscosity,
- Activation energy
1. [1]
  [1] 傅献彩, 姚天扬, 沈文霞等. 物理化学(第五版). 北京: 高等教育出版社, 2007.
2. [2]
  [2] Y Hu. Physical Chemistry (2^nd Ed.), Beijing, Higher Education Press, 2013.
3. [3]
  [3] I N Levine. Physical Chemistry (5^thEd.), McGraw Hill Press House, 2002.
4. [4]
  [4] R Chang. Physical Chemistry for the Chemical and Biological Science, University Science Books, 2000.
5. [5]
  [5] P Atkins, J de Paula. Physical Chemistry (7^th Ed.), Oxford University Press, 2002.
6. [6]
  [6] E Grunwald, K C Chang, J E Leffler. Ann. Rev. Phys. Chem., 1976, 27: 369~385.
7. [7]
  [7] K A Swiss, R A Firestone. J. Phys. Chem.A, 1999, 103(27): 5369~5372.
8. [8]
  [8] S Goldstein, G Czapski. J. Am. Chem. Soc., 1999, 121(11): 2444~2447.
9. [9]
  [9] A Kumar, S Pawar. Sci. China Chem., 2012, 55(8): 1633~1637.
10. [10]
  [10] J Katzer, W Pauer, H U Moritz. Macromol. React. Eng., 2012, 6(5): 213~224.
11. [11]
  [11] G van der Zwan, J T Hynes. J. Chem. Phys., 1983, 78(6): 4174~4185.
12. [12]
  [12] E del Rio, P Aplincourt, M F Ruiz-Lopez. Chem. Phys. Lett., 1997, 280(5~6): 444~450.
13. [13]
  [13] M Orozco, F J Luque. Chem. Rev., 2000, 100(11): 4187~4225.
14. [14]
  [14] M Orozco, F J Luque, D Habibollahzadeh et al. J. Chem. Phys., 1995, 102(15): 6145~6152.
15. [15]
  [15] R G Makitra, N M Karpyak, G G Midyana et al. Rus. J. Gen. Chem., 2010, 80(9): 1786~1791.
16. [16]
  [16] R Bini, C Chiappe, V L Mestre et al. Org. Biomol. Chem., 2008, 6(14): 2522~2529.
17. [17]
  [17] A Kumar, D Sarma. ACS Symp. Ser., 2005, 902: 350~370.
18. [18]
  [18] C Chiappe, D Pieraccini. J. Org. Chem., 2004, 69(18): 6059~6064.
19. [19]
  [19] 赵学庄, 罗渝然, 臧雅茹等. 化学反应动力学原理. 北京: 高等教育出版社, 1990, 789.
20. [20]
  [20] K H Kim, J Kim, J H Lee et al. Struct. Dyn., 2014, 1(1): 011301.
21. [21]
  [21] W Q Wu, C F Yang, H M Zhao et al. J. Chem. Phys., 2010, 132(12): 124510.
22. [22]
  [22] B Sipp, R Voltz. J. Chem. Phys., 1985, 83(1): 157~165.
23. [23]
  [23] M Orozco, C Colominas, F J Luque. Chem. Phys., 1996, 209(1): 19~29.
24. [24]
  [24] A Kumar, S S Deshpande. J. Org. Chem., 2003, 68(13): 5411~5414.
25. [25]
  [25] A F Olea, J K Thomas. J. Am. Chem. Soc., 1988, 110: 4494~4502.
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沈阳化工大学材料科学与工程学院沈阳 110142