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Citation: Zhang Xiaopeng, Li Zhengwei, Wang Yan, Niu Xueli, Zhang Guisheng. Selenium-Catalyzed Carbonylation to Diuron[J]. Chemistry, ;2016, 79(12): 1192-1195. shu

Selenium-Catalyzed Carbonylation to Diuron

1.
Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007

Received Date: 16 April 2016
Available Online: 10 August 2016
Fund Project:

A facile, green approach to diuron is reported. Using cheap, well-available nonmetal selenium as catalyst, CO instead of virulent phosgene as the carbonylation reagent, the target product can be obtained directly by one-pot selenium-catalyzed redox carbonylation of 3,4-dichloronitrobenzene with dimethylamine hydrochloride. The optimal reaction conditions were obtained through experimental researches on reaction time, temperature, kinds of solvents and bases, CO pressure and mole ratio of dimethylamine hydrochloride to 3,4-dichloronitrobenzene etc. Under the optimal reaction conditions, the target product can be obtained in 70% yield. Thus, a brief, simple, low-cost, high atom economic, and environmentally friendly approach to diuron is developed. A plausible route to diuron was presented at the end of this paper.
- Selenium catalyst,
- Carbonylation,
- Diuron
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