Citation: Ding Yang, Yang Yi, Ren Xuehong, Li Rong, Huang Dan. Synthesis and Characterizations of Water-Soluble Glycosylated UV-Absorber[J]. Chemistry, ;2016, 79(12): 1161-1165. shu

Synthesis and Characterizations of Water-Soluble Glycosylated UV-Absorber

Ding Yang ¹ ,
Yang Yi ¹ ,
Ren Xuehong ¹ ,
Li Rong ¹ ,
Huang Dan ^1,2,,

1.
1. Education Ministry Key Laboratory of Science & Technology for Eco-textiles, Jiangnan University, Wuxi 214122;
2.
2. Jiangsu Engineering Technology Research Center for Functional Textiles, Jiangnan University, Wuxi 214122

Corresponding author: Huang Dan,
Received Date: 19 May 2016
Available Online: 15 August 2016

A reactive water-soluble UV-absorber, (4-((4-chloro-6-(((2R,3R,4R,5S)-2-(2,2-dimethyl-1,3-dioxolan-4-yl) -4,5-dihydroxytetrahydrofuran-3-yl)oxy)-1,3,5-triazin-2-yl)oxy)-2-hydroxyphenyl)(phenyl) methanone (UV-DTM), was synthesized by using 2,4-dihydroxy benzophenone (UV-0), diacetone glucose and 2,4,6-trichloro-1,3,5-triazine (TCT) as the main raw materials. The structure was confirmed by IR, NMR and MS. The highest yield (73%) of DTDT can be obtained in the conditions:n (TCT):n (diacetone glucose):n (NaOH)=0.9:1:1.7 and 0℃, 8 h. The highest yield (74%) of UV-DT can be obtained in the conditions:n (DTDT):n (UV-0):n(NaOH)=1:1.1:1 and 30℃, 2 h. The highest yield (74%) of UV-DTM can be obtained in the conditions:0.5 mL hydrochloric acid (36%) with each millimole of UV-DT, 25℃, 5 h. The UV-absorption of UV-DTM in 240~400 nm was strong, and its water solubility was improved.
- UV-absorber,
- 2,4-Dihydroxy-benzophenone,
- Diacetone glucos,
- 2,4,6-Trichloro-1,3,5-triazine
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