Citation: Ding Mingzhu, Gao Jian, Li Dongdong, Lian Honglei. Syntheses and Applications of Core-Shell Structure Magnetic Nanoparticles Supported Ionic Liquids[J]. Chemistry, ;2016, 79(12): 1106-1112. shu

Syntheses and Applications of Core-Shell Structure Magnetic Nanoparticles Supported Ionic Liquids

1.
Research Center of Heterogeneous Catalysis and Engineering Science, School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001

Corresponding author: Lian Honglei,
Received Date: 10 March 2016
Available Online: 18 May 2016
Fund Project:

Ionic liquids (ILs) have excellent solubility and stability, structure tunability and negligible vapor pressures, which make them be suitable reaction media for organic synthesis and catalyst. However, the large-scale application of ILs is still far from realization because of their high cost and difficult recovery. Superparamagnetic nanoparticles can be simply and efficiently removed from reaction mixtures with an external magnetic field. However, they are sensitive to agglomeration and can't be stably dispersed in the reaction system due to their high specific surface energy and magnetic dipole interactions. Using organic or inorganic substance to coat magnetic nanoparticles can form a kind of core-shell structure composite materials, which not only prevent them from agglomerating but also in favour of surface functionalization. Therefore, the immobilization of ILs on the surface of core-shell structure magnetic nanoparticles and the preparation of recyclable heterogeneous catalysts has been widely concerned. In this paper, the preparation method of core-shell magnetic nanoparticles supported IL catalysts as well as their applications in organic synthesis are reviewed, and the direction of the further research is suggested.
- Ionic liquids,
- Core-shell structure,
- Magnetic nanoparticles,
- Catalyst support,
- Separation and recovery
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