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Citation: MA Yong-Ping, ZHAO Ge-Jian, TAO Hui-Wang, WANG Wei, LI Bin, WANG Jia-Qiang. Catalytic Oxidation of Tetralin to α-Tetralone with Hydrogen Peroxide over Cobalt Loaded MCM-41[J]. Chinese Journal of Applied Chemistry, ;2010, 27(1): 69-73. shu

Catalytic Oxidation of Tetralin to α-Tetralone with Hydrogen Peroxide over Cobalt Loaded MCM-41

a.
a. Department of Applied Chemistry, Key Laboratory of Medicinal Chemistry for Natural Resource, MOE, Yunnan University, Kunming 650091;
b.
b. Faculty of Science, Kunming University of Science and Technology, Kunming

Received Date: 3 January 2009
Available Online: 20 March 2009
Fund Project: "九七三"前期计划课题(2008CB617514) (2008CB617514)云南省自然科学基金项目(2007B018M和2008CD065) (2007B018M和2008CD065)云南省教育厅基金(K1050534) (K1050534)昆明理工大学校青年基金(2007-078) (2007-078)昆明理工大学分析测试基金(2008-080) 资助项目 (2008-080)

The conversions and selectivities of the oxidation of tetralin to α-tetralone in acetic acid with H₂O₂ as oxidant over transition metals(Fe,Co,Ni,Ce,Cu,La,Zr and Cr) loaded MCM-41 were compared.An excellent conversion of tetralin and high selectivity of α-tetralone were also obtained when Co/MCM-41 was used.The effects of reaction temperature,reaction time and catalyst concentration on the catalyst performance were examined in order to optimize the conversion of tetralin and selectivity of α-tetralone.A selectivity of 70.3% of tetralin to α-tetralone was obtained at 94.7% conversion of tetralin under the optimum reaction condition:m(tetralin):m(catalyst) =12.5:1;reaction temperature=383 K,reaction time=8 h.Co/MCM-41 act as a solid heterogeneous catalyst in the reaction system and it can be recycled three times without losing its activity to a great extent.
- cobalt loaded MCM-41,
- oxidation of the tetralin,
- α-tetralone
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