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Citation: ZHANG Qian, LIU Zhao-Di, LIU Hui-Jun, WU Jie-Ying, ZHOU Hong-Pin, YANG Jia-Xiang, TIAN Yu-Peng. Synthesis,Crystal Structure and Third-Order Nonlinear Optical Properties of Methanoanthracene-stilbazolium Tetraphenylborate[J]. Chinese Journal of Applied Chemistry, ;2010, 27(1): 58-62. shu

Synthesis,Crystal Structure and Third-Order Nonlinear Optical Properties of Methanoanthracene-stilbazolium Tetraphenylborate

a.
a. Department of Chemistry, Anhui Province Key Laboratory of Functional Inorganic Materials, Anhui University, Hefei 230039;
b.
b. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093

Received Date: 18 January 2009
Available Online: 29 July 2009
Fund Project: 国家自然科学基金(50532030,50703001,20771001) (50532030,50703001,20771001)安徽省高校省级科技创新团队基金(2006KJ007TD) (2006KJ007TD)教育部博士点基金(20050357001) 资助项目 (20050357001)

A novel substituent styryl pyridinium tetraphenylborate,4-N,N-dimethylamino-4'-N'-9-methano-anthracene-stilbazolium tetraphenylborate,was synthesized and characterized by means of IR,¹H NMR,¹³C NMR,MS-EI and X-ray single-crystal diffraction.The compound crystallized in the monoclinic space group P2₁/c with a=1.255 7(1) nm,b=1.539(1) nm,c=2.220 2(8)nm,β=101.099(1)°,and V=4.210 5(4)nm³,Z=4,D_c=1.159 g/cm³.The nonlinear optical properties of the compound were investigated by virtue of 1 064 nm nanosecond laser beam,and the results show that the novel pyridinium salt has a two photon absorption(TPA) coefficient of β=0.028 cm/GW,a TPA cross-section of σ=8.68×10^-48 cm⁴·s·photon^-1.
- substituent styryl pyridinium salt,
- nonlinear optical property,
- crystal structure,
- Z-scan
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