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Citation: Kuang Daizhi, Zhou Xiuzhong. Synthesis and Characterization of Tricarbonylhexamethylsilylcyclopentadienyl Molybdenum Derivatives[J]. Chinese Journal of Applied Chemistry, ;1995, 12(1): 38-42. shu

Synthesis and Characterization of Tricarbonylhexamethylsilylcyclopentadienyl Molybdenum Derivatives

Kuang Daizhi ¹ ,
Zhou Xiuzhong ²

1.
1. Department of Chemistry, Hengyang Teacher's College, Hengyang 421008;
2.
2. Department of Chemistry, Nankai University, Tianjin

Received Date: 19 April 1994
Available Online: 6 September 1994
Fund Project:

The alkyl-molybdenum compounds were synthesized via reactions of tricar-bonylpentamethyldisilanyicyclopentadienyl molybdenum anion saIt with alkyl halide(ethyl-chloroacetate,benzyl chloride,ethyliodide,1,4-diiodobutane).The hexamethyltrisiloxyl-bridged-bis(tricarbonylcyclopentadienyl molybdenum anion salt)was treated with glacial acetic acid and followed reacted with ferric sulfate to produce the oxidative coupling molybd-num-molybdenum dinuclear compound.HexamethyItrisiloxyl-bridged bis(tricarbonyl-cyclopentadienyliodo-molybdenum)compound was formed by cleavage of molybdenum-molybdenum bond with iodine.The structures of title compounds were characterized by ele-mental analysis,IR and ¹H NMR measurements.
- pentamethyldisilanylcyclopentadiene,
- hexamethyltrisiloxylbridged biscyclopen-tadiene,
- molybdenum anion,
- alkylation reaction,
- oxidative coupling
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