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Citation: Li Xiaoli, Yu Guangqian, Li Yuliang, Qu Yahuan, Su Shugui, Yin Zuorui. STUDY ON POLY(STYRENE-4-VINYLPYRIDINE)NEODYMIUM COMPLEX[J]. Chinese Journal of Applied Chemistry, ;1993, 10(6): 92-94. shu

STUDY ON POLY(STYRENE-4-VINYLPYRIDINE)NEODYMIUM COMPLEX

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022 Changchun

Received Date: 16 March 1993
Available Online: 7 June 1993
Fund Project:

Poly (styrene-4-vinylpyridine)-neodymium complexes (NdCl₃·PS₄VPY) with various contents of the functional group and neodymium have been prepared and characterized. The infrared and X-ray photoelectron spectra indicate that the uncoordinated 4vinylpyridine (4VPY) units remain in the NdCl₃·PS₄VPY complexes. A novel binary catalytic system for butadiene polymerization can be formed from NdCl₃·PS₄VPY and iBu₃Al, showing a catalytic activity much greater than the similar low molecular catalysts.
- poly (styrene-4-vinylpyridine),
- neodymium complex,
- infrared spectrum
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