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Citation: Pan Pinglai, Liu Zhongyang, Yuan Guoqing, Jiang Dazhi. SYNTHESIS, STRUCTURE OF CIS-DICARBONYL RHODIUM(Ⅰ) COPOLYMER COMPLEXES AND THEIR CATALYTIC PROPERTY FOR METHANOL CARBONYLATION[J]. Chinese Journal of Applied Chemistry, ;1993, 10(5): 72-74. shu

SYNTHESIS, STRUCTURE OF CIS-DICARBONYL RHODIUM(Ⅰ) COPOLYMER COMPLEXES AND THEIR CATALYTIC PROPERTY FOR METHANOL CARBONYLATION

1.
Institute of Chemistry, Chinese Academy of Sciences, 100080 Beijing

Received Date: 15 October 1992
Available Online: 20 May 1993

A series of 4-vinyl pyridine-methyl acrylate copolymer complexes with tetracarbonyldichlorodirhodium were prepared. Their structure characteristics and catalytic properties for methanol carbonylation to synthesize acetic acid have been studied. The macromolecular complexes containing cis-dicarbonyl rhodium in structure have a higher catalytic activity in methanol carbonylation and an excellent thermal stability. There appeared two coordination units in the copolymer complexes: x=0，1,2 The carbonylation of methanol catalyzed by the complexes can be carried out in mild conditions with-out any side-products. The selectivity of carbonylation reaction was approximately 100%.
- vinyl pyridine,
- methyl acrylate,
- copolymer,
- cis-dicarbonyl rhodium complex,
- methanol carbonylation,
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