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Citation: Chen Zuxing. STUDIES ON THE APPLICATION OF EQUIVALENTS TO SYNTHESIS Ⅵ. A NOVEL ROUTE TO THE SYNTHESIS OF DIHYDROJASMONE[J]. Chinese Journal of Applied Chemistry, ;1993, 10(4): 92-94. shu

STUDIES ON THE APPLICATION OF EQUIVALENTS TO SYNTHESIS Ⅵ. A NOVEL ROUTE TO THE SYNTHESIS OF DIHYDROJASMONE

Chen Zuxing

1.
Department of Chemistry, Hubei University, 430062 Wuhan

Received Date: 2 December 1992
Available Online: 15 March 1993

A novel route for dihydrojasmone synthesis is reported. The main strategy inolves the nucleophilic substitution using ethyl α-cyanoheptyl carbonate (2) as acyl-anion(=O) equivalents to bromide (3),following by hydrolysis to give the undecane-2,5-dione (5) which by base cyclization afforded dihydrojasmone (6). The method is simple and carried out in mild reaction conditions.
- dihydrojasmone,
- synthesis,
- equivalent
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