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Citation: Xie Fuxin, Tian Yupeng, Xu Zhiqiang, Ni Shisheng. SYNTHESIS OF 1,2-BIS(1,12-DIAZA-3,4:9,10-DIBENZO-5,8-DIOXACYCLOPENTADECANE-N-ACETIC ACID)ETHANE AND ITS LANTHANIDE COMPLEXES[J]. Chinese Journal of Applied Chemistry, ;1993, 10(4): 22-25. shu

SYNTHESIS OF 1,2-BIS(1,12-DIAZA-3,4:9,10-DIBENZO-5,8-DIOXACYCLOPENTADECANE-N-ACETIC ACID)ETHANE AND ITS LANTHANIDE COMPLEXES

Xie Fuxin ^1,2 ,
Tian Yupeng ^1,2 ,
Xu Zhiqiang ^1,2 ,
Ni Shisheng ^1,2

1.
Department of Chemistry, Anhui University, 230039 Hefei
2.

Received Date: 18 August 1992
Available Online: 6 November 1992
Fund Project:

The synthesis and characterization of a new bis-N-functionalized diaza-dioxa maeroeycle 1,2-his(1, 12-diaza-3, 4:9,10-dibenzo-5, 8-dioxaeyclopentadeeane-N-aeetie aeid) ethane (H₂L²) are reported. Eight lanthanide (La, Pr, Nd, Sm, Eu, Gd, Dy, Yb) complexes with this ligand have been prepared in methanol solution by the reaction of H₂L² with rare earth nitrate respectively. These complexes have a general formula of Ln₂L²(NO₃)₄·nH₂O. Their coordination properties are discussed.
- bis-N-acetic acid substituted diaza-dioxa macrocycle,
- rare earth,
- complex,
- synthesis
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