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Citation: Qi Yulan, Yang Rudong. SYNTHESIS AND CHARACTERIZATION OF TERNERY COMPLEXES OF RARE EARTHS WITH HPMBP AND 1-NITROSO-2-NAPHTHOL[J]. Chinese Journal of Applied Chemistry, ;1993, 10(4): 10-12. shu

SYNTHESIS AND CHARACTERIZATION OF TERNERY COMPLEXES OF RARE EARTHS WITH HPMBP AND 1-NITROSO-2-NAPHTHOL

Qi Yulan ,
Yang Rudong

1.
Department of Chemistry, Lanzhou University, 730000 Lanzhou

Received Date: 3 September 1992
Available Online: 8 March 1993

Sixteen cornplexes of rare earth (RE=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y) with 1-pheny-3-methyl-4-benzoyl-pyrazolone-5 (HPMBP) and 1-nitroso-2-naphthol (NN) have been synthesized and characterized by elemental analysis, IR ¹H NMR and DTA measurements. The ternary complexes have a general formula RE:PMBP:NN=1:3:1(1:4:1 when RE=Ce(Ⅳ)). All the complexes are crystal in gray-violet colour. They are soluble in ethanol, acetone and benzene, insoluble in water, and air-stable at room temperature.
- rare earth,
- phenylmethylbenzoylpyrazolone,
- nitrosonaphthol,
- ternary complex,
- synthesis
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