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Citation: Sun Junquan, Wang Guangming, Shen Zhiquan. COORDINATION POLYMERIZATION OF BUTYL METHACRYLATE WITH Nd(Oct)₃-Al(i-Bu)₃[J]. Chinese Journal of Applied Chemistry, ;1993, 10(4): 1-4. shu

COORDINATION POLYMERIZATION OF BUTYL METHACRYLATE WITH Nd(Oct)₃-Al(i-Bu)₃

1.
Department of Polymer Science and Engineering, Zhejiang University, 310027 Hangzhou

Received Date: 2 December 1992
Available Online: 15 March 1993
Fund Project:

In the polymerization of butyl methacrylate catalyzed by Nd(Oct)₃-Al(i-Bu)₃, the conversion in hexane and petroleum ether was found to be higher than that observed in toluene and tetrahydrofuran. The combination of Al(i-Bu)₃ with Nd(Oct)₃ gave the polymer of higher molecular weight than other Nd-complexes:Nd(P₂₀₄)₃, Nd(P₅₀₇)₃ and Nd(naph)₃. Kinetics study showed that the rate of polymerization is first order with respect to the monomer and catalyst concentration. The activation energy of polymerization of butyl methacrylate is 47.4kJ/mol.
- butyl methacrylate,
- coordination polymerization,
- neodymium complex,
- Ziegler-Natta catalyst
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COORDINATION POLYMERIZATION OF BUTYL METHACRYLATE WITH Nd(Oct)3-Al(i-Bu)3

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

COORDINATION POLYMERIZATION OF BUTYL METHACRYLATE WITH Nd(Oct)₃-Al(i-Bu)₃