Citation:
Li Jun, Gao Shiyang, Qu Jingnian, Qu Songsheng. CHEMISTRY OF BORATE IN SALT LAKE BRINE ⅩⅤ. THERMOCHEMICAL STUDY OF Mg-BORATES[J]. Chinese Journal of Applied Chemistry,
;1993, 10(3): 12-15.
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The enthalpies of solution of two Mg-borates(2MgO·2B2O3·MgCl2·14H2O and MgO·2B2O3·9H2O) in 0.997mol/L HCl solution were measured by using isoperibel reaction colorimeter.The standard enthalpies of formation of the two Mg-borate salts were obtained according to thermochemistry theory. The values are -8638.42kJ/tool and -5807.07k J/mol separately. The standard molar entropy of MgO·2B2O3·9H2O was also given.
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