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Citation: Zhang Hesheng, Chen Jiawei, Jiang Jilong. A FACILE SYNTHETIC METHOD OF 8-SUBSTITUTED GERANIOL[J]. Chinese Journal of Applied Chemistry, ;1993, 10(2): 104-106. shu

A FACILE SYNTHETIC METHOD OF 8-SUBSTITUTED GERANIOL

1.
Department of Chemistry, Hubei University, 430062 Wuhan

Received Date: 29 April 1992
Available Online: 18 September 1992
Fund Project:

10, 11-Dihydrofarnesol (3_a) and 6,7-dehydrophytol (3_b), which are important in perfume and synthesis of vitamin E and K₁, were prepared by reacting 6-chloro-3, 7-dimethyl-2, 7-octadi-enylpyrane (1) with isoamylmagnesium bromide and 3,7-dimethyloctylmagnesium bromide, respectively.
- ene chlorination,
- substituted geraniol,
- Grignard reagent,
- coupling reaction,
- synthesis
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