引用本文:
贾殿赠, 李昌雄, 忻新泉. 固相配位化学反应研究LV.FeCl2·4H2O,CoCl2·6H2O,NiCl2·6H2O,CuCl2·2H2O与邻菲咯啉的低热固相化学反应研究[J]. 应用化学,
1993, 10(1): 110-112.
Citation: Jia Dianzeng, Li Changxiong, Xin Xinquan. STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS LV. INVESTIGATION OF SOLID STATE REACTIONS OF PHENANTHROLINE WITH METAL CHLORIDES(M=Fe,Co,Ni,Cu)[J]. Chinese Journal of Applied Chemistry, 1993, 10(1): 110-112.
Citation: Jia Dianzeng, Li Changxiong, Xin Xinquan. STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS LV. INVESTIGATION OF SOLID STATE REACTIONS OF PHENANTHROLINE WITH METAL CHLORIDES(M=Fe,Co,Ni,Cu)[J]. Chinese Journal of Applied Chemistry, 1993, 10(1): 110-112.
固相配位化学反应研究LV.FeCl2·4H2O,CoCl2·6H2O,NiCl2·6H2O,CuCl2·2H2O与邻菲咯啉的低热固相化学反应研究
English
STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS LV. INVESTIGATION OF SOLID STATE REACTIONS OF PHENANTHROLINE WITH METAL CHLORIDES(M=Fe,Co,Ni,Cu)
Abstract:
Solid state reactions of metal chlorides (M=Fe, Co, Ni, Cu) with Phenanthroline at room temperature have been studied. A two-step addition reaction was observed. The intermediates M(Phen)2Cl2·nH2O(M=Co,Ni,Cu) were confirmed by experimental results. Effects of molecular structure of the reactants and the stability of the complexes formed were also discussed.
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Key words:
- solid state reaction
- / phenanthroline
- / transition metal chloride
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