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Citation: HAO Fu-Ying, YIN Jian-Hui, GAN Xiao-Ping, GENG Wen-Qian, XU Guo-Yi, WU Jie-Ying, TIAN Yu-Peng, ZHOU Hong-Ping. Solid-state Synthesis of Carbazole Derivatives and Their Two-photon Absorption and Optical Storage Properties[J]. Chinese Journal of Applied Chemistry, ;2009, 26(11): 1277-1281. shu

Solid-state Synthesis of Carbazole Derivatives and Their Two-photon Absorption and Optical Storage Properties

1.
a Department of Chemistry and Chemical Engineering, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230039;
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b Department of Chemistry and Chemical Engineering, Fuyang Normal College, Fuyang

Corresponding author: ZHOU Hong-Ping,
Received Date: 3 November 2008
Available Online: 18 January 2009
Fund Project: 国家自然科学基金(50703001,20771001) (50703001,20771001)安徽省高校青年教师科研资助计划(2007jq1019) (2007jq1019)安徽省高校省级科技创新团队基金(2006KJ007TD) (2006KJ007TD)阜阳师范学院科研基金(2002YJL04) (2002YJL04)

2,8-Bis[2'-(4″-pyridyl)ethenyl]-5-ethylcarbazole and 2,8-bis[2'-(2″-pyridyl)ethenyl]-5-ethylcarbazole were synthesized from N-ethyl carbazole at room temperature via a solid-state reaction.Their structures were characterized by ¹H NMR,IR and MS.Two-photon absorption cross-sections were obtained by Z-scan technique.The femtosecond single pulse laser(820 nm) as writing laser was applied to the storage medium for two-photon photobleaching,indicating that they would be three-dimensional optical storage materials.
- N-ethyl carbazole,
- vinyl pyridine derivative,
- solid-state reaction,
- two-photon absorption,
- photo-bleaching storage
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