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Citation: CAI Ke-Ying, LIU Chang-Ning, ZHOU Ying-Mei, YUE Wei. Reduction of Aromatic Nitro Compounds with Hydrazine Hydrate Catalyzed by Bismuth Oxide Hydroxide Supported on Activated Carbon[J]. Chinese Journal of Applied Chemistry, ;2009, 26(9): 1080-1083. shu

Reduction of Aromatic Nitro Compounds with Hydrazine Hydrate Catalyzed by Bismuth Oxide Hydroxide Supported on Activated Carbon

1.
School of Chemistry and Chemical Engineering, Xuzhou Institute of Technology, Xuzhou 221006

Corresponding author: CAI Ke-Ying,
Received Date: 25 August 2008
Available Online: 10 November 2008
Fund Project: 徐州工程学院科研项目(XKY2007242) (XKY2007242)

BiO(OH)/C catalysts were prepared by the impregnation of activated carbon in a bismuth nitrate solution.XRD patterns of the catalysts show that BiO(OH) was well-dispersed in activated carbon when the mass percent of BiO(OH) in catalyst is no more than 10%.At 75 ℃,the catalytic activity was maintained after 7 runs.In 5 mL of ethanol,1 mmol of aromatic nitro compounds reacted with 2 mmol of hydrazine hydrate in the presence of 0.05 g of 10%BiO(OH)/C,at 75 ℃ and for a certain period of time,a yield of 88%~99% is obtained for producing anilines.
- bismuth oxide hydroxide,
- reduction,
- aromatic nitro compound,
- hydrazine hydrate,
- anilines
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