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Citation: BING Bai-Chun, LI Bin, JIA He, YANG Ming-Fei. Synthesis and Thermal Properties of Hexa[p-(carboxyl)phenoxy]cyclotriphosphazene[J]. Chinese Journal of Applied Chemistry, ;2009, 26(7): 753-756. shu

Synthesis and Thermal Properties of Hexa[p-(carboxyl)phenoxy]cyclotriphosphazene

1.
Heilongjiang Key Laboratory of Molecular Design and Preparation of Flame Retarded Materials, College of Science, Northeast Forestry University, Harbin 150040

Corresponding author: LI Bin,
Received Date: 16 June 2008
Available Online: 20 August 2008
Fund Project: 国家自然科学基金资助项目(20774016) (20774016)

Hexa[p-(carboxyl) phenoxy]cyclotriphosphazene(HCPCP) was synthesized via two steps.Firstly,hexa[p-(aldehyde) phenoxy]cyclotriphosphazene(HAPCP) was obtained via a nucleophilic substitution of hexachlorocyclotriphosphazene with 4-hydroxybenzaldehyde.Then HCPCP was synthesized via potassium permanganate oxidation and characterized by infrared spectroscopy(IR),high performance liquid chromography(HPLC),nuclear magnetic resonance(NMR) and elemental analysis.Thermal properties of the macromolecule were investigated by thermogravimetric analysis(TGA) and differential scanning calorimetry(DSC).With the addition of 30%HCPCP,the limiting oxygen index(LOI) of ABS was increased to 25%.
- hexachlorocyclotriphosphazene,
- hexa[p-(carboxyl)phenoxy]cyclotriphosphazene,
- synthesis,
- thermal behavior
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