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Citation: HU Zhen, LIN Mei-Juan. (C₈H₁₅O₂)_x(C₁₂H₂₃O₂)_yEu/PMMA Luminescent Material[J]. Chinese Journal of Applied Chemistry, ;2009, 26(6): 646-650. shu

(C₈H₁₅O₂)_x(C₁₂H₂₃O₂)_yEu/PMMA Luminescent Material

HU Zhen ,
LIN Mei-Juan ^,

1.
College of Chemistry and Materials, Fujian Normal University, Fuzhou 350007

Corresponding author: LIN Mei-Juan,
Received Date: 27 June 2008
Available Online: 1 September 2008
Fund Project: 福建省自然科学基金资助项目(2006J0250) (2006J0250)

New europium complexes(C₈H₁₅O₂)_x(C₁₂H₂₃O₂)_yEu,which is soluble in MMA monomer,were synthesized with caprytlic acid(C₈H₁₅O₂) and lauric acid(C₁₂H₂₃O₂) as the first ligand by saponification method.Photoluminescent PMMA containing rare earth complexes A_xB_yEu/PMMA(A=—C₈H₁₅O₂,B=—C₁₂H₂₃O₂,x,y was their mol ratio) were prepared by bulk polymerization.The effects of different second ligands(carbazole,dmbp,phen,HTTA) on the flourescent properties of the polymers were studied.Then AxByEu/HTTA/PMMA was prepared with ligand HTTA.The structures and fluorescence properties of the complexes and polymers containing europium were investigated by IR,UV and Fluorescence spectra.Results indicate that the polymers obtained emit strong characteristic luminescence of Eu³⁺ ions.Notably even if the mass fraction of HTTA was 0.02%,it could enhance the characteristic red luminescence of(C₈H₁₅O₂)₃Eu/HTTA/PMMA greatly,while the transparency of the polymer was not affected.
- caprylic acid,
- lauric acid,
- rare earth europium,
- luminescence,
- polymer
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(C₈H₁₅O₂)_x(C₁₂H₂₃O₂)_yEu/PMMA Luminescent Material