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Citation: HONG Yong, XIAO Jing-Yi, HUANG Ke-Long, Yu Jin-Gang, HUANG Du-Shu. Structure and Fluorescence Properties of Bis-Schiff-base-5-fluorosalicylaldehyde-o-Phenylenediamine and Its Zn(Ⅱ) Complex[J]. Chinese Journal of Applied Chemistry, ;2009, 26(5): 607-612. shu

Structure and Fluorescence Properties of Bis-Schiff-base-5-fluorosalicylaldehyde-o-Phenylenediamine and Its Zn(Ⅱ) Complex

1.
Institute of Functional Materials and Chemistry, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083

Corresponding author: HUANG Ke-Long,
Received Date: 24 July 2008
Available Online: 9 December 2008

Bis-Schiff-base-5-fluorosalicylaldehyde-o-phenylenediamine was prepared.The crystal and molecular structure was investigated by X-ray analysis.The crystal is in the monoclinic space group P2(1)/c with a=0.609 38(8),b=1.634 7(2),c=9.447 4(2),V=165.19(4) nm³,Z=4,D_c=1.417,μ(MoKα)=0.11 mm,F(000)=728,T=293 K,R=0.032.The Zn(Ⅱ) complex(C₂₀H₁₂F₂N₂O₂Zn) was prepared and characterized by the analytical and spectroscopic methods and its fluorescence properties were also studied in the solution and in the solid state.
- Schiff base,
- complex,
- crystal structure,
- fluoresence
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