Citation:
HU Qing-Hong, YUAN Ze-Li, WU Qing, ZHANG Ming-Qin, ZHU Bi-Xue. Study on Synthesis and Antibacterial Activity of the Binuclear Complexes with Dithiocarbohydrazones Schiff Base as Ligand[J]. Chinese Journal of Applied Chemistry,
;2009, 26(5): 534-537.
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A binuclear Schiff base ligand was synthesized via the reaction of 3-carboxylsalicylaldehyde and dithiocarbohydrazon.The cobalt(Ⅱ),copper(Ⅱ),nickel(Ⅱ) and zinc(Ⅱ) complexes were also synthesized via the complexation of the resulting ligand to the corresponding metal ions with yields of 57%~78%,and characterized by elementalan alysis,1H NMR,IR,UV-Vis,molar conductance and MS.The antiba-cterial activities of the compounds were tested against seven kinds of bacteria.The results show that the compounds possess different inhibiting effects.
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Keywords:
- dithiocarbohydrazon,
- Schiff Base,
- binuclear complex,
- metal ions,
- synthesis
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