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Citation: MA Li, HE Ya-Bing, JIN Ri-Zhe, BIAN Zheng, GAO Lian-Xun. Synthesis and X-ray Crystal Structure and Catalytic Properties of Molybdenum(Ⅵ) Complex with 3-{6[(1R,2R,4S)-2-Hydroxy-1,3,3-Trimethylbicyclo Heptan-2-yl]Pyridine-2-yl}-2'-Pivaloyloxy-(R)-BINOL[J]. Chinese Journal of Applied Chemistry, ;2009, 26(5): 519-522. shu

Synthesis and X-ray Crystal Structure and Catalytic Properties of Molybdenum(Ⅵ) Complex with 3-{6[(1R,2R,4S)-2-Hydroxy-1,3,3-Trimethylbicyclo Heptan-2-yl]Pyridine-2-yl}-2'-Pivaloyloxy-(R)-BINOL

1.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Graduate School of Chinese Academy of Sciences, Changchun 130022

Corresponding author: GAO Lian-Xun,
Received Date: 14 April 2008
Available Online: 5 July 2008
Fund Project: 国家自然科学基金资助项目(B020104) (B020104)

Reaction of MoO₂(acac)2 with 3-{6-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicycloheptan-2-yl]pyridine-2-yl}-2'-pivaloyloxy-(R)-BINOL(2),synthesized from 3-{6-[(1R,2R,4S)-2-hydroxy-1,3,3-trime-thylbicycloheptan-2-yl]pyridine-2-yl}-(R)-BINOL(1) and pivaloyl chloride,afforded the chiral molybdnum complex 2(Mo(Ⅵ)-2).The compound Mo(Ⅵ)-2 was charactierized by ¹H NMR,IR,ESI-MS and X-ray single crystal diffraction.The crystatal belongs to monoclinic system with space group P21,a=1.179 34(10) nm,b=2.304 5(2) nm,c=1.518 88(13) nm,α=90°,β=112.84°,γ=90°,V=3.804 2(6) nm³,Z=4,μ=0.392 mm^-1,D_c=1.298 Mg/m³,F(000)=1 544,R¹=0.077 5,wR²=0.193 4,GOF=1.122.In this molecule,the Mo(Ⅵ) atom exists in a coordination environment with one water molecule and one tridentate ONO ligand in compound 2.This chiral molybdenum complex was found to catalyse the epoxidation of 2-vinylnaphthalene in 7%e.e..
- (hydroxymethylpyridinyl)-BINOL,
- molybdnum(Ⅵ) complex,
- crystal structure,
- asymmetric catalysis
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