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Citation: ZHANG Ming-Zhu, SHEN Yong-Miao, WANG Bing-Xiang, QI Chen-Ze. Synthesis of Some Indolizine Derivatives and Their Absorption Spectra[J]. Chinese Journal of Applied Chemistry, ;2009, 26(5): 515-518. shu

Synthesis of Some Indolizine Derivatives and Their Absorption Spectra

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a College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua;
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b Department Chemistry, Shaoxing University, Shaoxing 312000;
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c College of Chemistry Environment Science, Nanjing Normal University, Nanjing

Corresponding author: SHEN Yong-Miao,
Received Date: 6 May 2008
Available Online: 11 September 2008
Fund Project: 绍兴市有机化学重点学科、绍兴文理学院校级科研项目(07LG1004)资助 (07LG1004)

Four novel azo derivatives of indolizine were synthesized and fully characterized by ¹H and ¹³C NMR,FTIR,elemental analysis,and thermal analysis.The behaviour of these diazo dyes in various solvents was evaluated.Substituent,acid and base effects on the visible absorption maxima of the dyes were also reported.The absorption maxima displayed a blue-shift when the compounds were present under ionic condition.DSC curves show that the decomposition temperature for the compound having alkyl substituent at the C-2 position is 180 ℃.2-Phenyl-substituted compounds are comparatively stable,with a decomposition temperatures above 200 ℃.
- indolizine,
- azo dyes,
- UV spectroscopy
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