Citation:
LI Sheng-Ying, WEI Yun-Xia, MA Ming-Guang, GAO Jin-Zhang, YANG Wu. Preparation of PPy/SnO2/CA Nanocomposite Film and Its Photocatalytic Activity for the Synthesis of PMMA[J]. Chinese Journal of Applied Chemistry,
;2009, 26(4): 413-420.
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Polypyrolle/SnO2(PPy/SnO2) nanocomposite particles(~30 nm) was synthesized by the emulsion polymerization in the presence of (NH4)2S2O8 as oxidant.PPy/SnO2/cellulose acetate(PPy/SnO2/CA) nanocomposite film was prepared with cellulose acetate as film former and acetone as solvent.The crystal structure,surface morphology,absorption spectra and the thermic stability of the products were investigated by TG,XRD,TEM,SEM,AFM,FT-IR,and DRS techniques.The photocatalytic activities of the products were evaluated by the polymerization of MMA.The average diameter and mass-average molecular mass of poly(methyl methacrylate)(PMMA) particles are 18 nm and 1.42×105,respectively.
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Keywords:
- PPy/SnO2/CA,
- nanocomposite film,
- synthesis,
- photocatalysis,
- PMMA
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