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Citation: LIU Xiu-Ying, ZHANG Chao-Can, CUI Wei-Gang, XU Wei-Lin. An Improved Method for Synthesis of Allyl Glycidyl Ether[J]. Chinese Journal of Applied Chemistry, ;2009, 26(3): 370-372. shu

An Improved Method for Synthesis of Allyl Glycidyl Ether

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a School of Materials Science and Engineering, Wuhan Universiy of Technology, Wuhan 430070;
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b College of Chemical Engineering, Wuhan College of Science and Engineering, Wuhan;
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c Research Centre of Textile, Wuhan College of Science and Engineering, Wuhan

Corresponding author: ZHANG Chao-Can,
Received Date: 17 March 2008
Available Online: 13 June 2008
Fund Project: 湖北教育厅资助项目(B200717002) (B200717002)

Sodium allylate was prepared from solid sodium hydroxide and allyl alcohol under mild conditions,and then the solid sodium allylate was reacted with epichlorohydrin in anhydrous system to produce allyl glycidyl ether in high yield and purity.Effects of ratio of sodium allylate to epichlorohydrin,reaction temperature and time and way of adding materials on the yield of allyl glycidyl ether were investigated.Sodium allylate can be obtained in a high yield when the molar ratio of solid sodium hydroxide to allyl alcohol was 1 to 3.The yield of allyl glycidyl ether can reach up to 96% at 30 ℃ for 3 h at a molar ratio of 1 to 1.5 of sodium allylate to epichlorohydrin.
- allyl glycidyl ether(allyloxyepoxypropane),
- epichlorohydrin,
- sodium allylate,
- allyl alcohol,
- synthesis
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