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Citation: BAI Li-Juan, LEI Fu-Hou, PAN Peng-Hui, YANG Sheng-Cai, SUN Guo-Song. Synthesis of Nickelous Complex of Disproportionated Rosin Amine Schiff Base and Its Catalytic Performance for Oxidation of Abietic Acid[J]. Chinese Journal of Applied Chemistry, ;2009, 26(3): 297-301. shu

Synthesis of Nickelous Complex of Disproportionated Rosin Amine Schiff Base and Its Catalytic Performance for Oxidation of Abietic Acid

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a College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning 530006;
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b Key Laboratory of Development and Application of Forest Chemicals of Guangxi, Nanning 530006;
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c Guangxi Research Institute of Chemical Industry, Nanning

Corresponding author: LEI Fu-Hou,
Received Date: 21 February 2008
Available Online: 30 May 2008
Fund Project: 国家民族事务委员会科研基金资助项目(05GX03) (05GX03)

Disproportionated rosin amine Schiff base was synthesized from disproportionated rosin amine.The ligand and its nickel complex were characterized with FTIR,UV,elemental analysis etc.The catalytic performance of the nickel complex for the oxidation of abietic acid was studied.The influences of solvent,H₂O₂ concentration,reaction temperature and time were investigated.The results show the catalyst has good catalytic performance for the oxidation and polymerization of abietic acid,and the conversion of abietic acid reaches to 100%.
- disproportionated rosin amine Schiff base,
- nickelous complex,
- abietic acid,
- oxidation
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