Citation:
XIN Bing-Wei. Synthesis of Chalcones in IL-H2O System[J]. Chinese Journal of Applied Chemistry,
;2009, 26(1): 47-50.
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The palladium acetate-catalyzed synthesis of chalcones in water in the presence of 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][ PF6]) is described.The Pd(OAc)2-[bmim][PF6]-H2O catalytic system can be recovered and reused six times with high efficiency.Compared with previous methods in organic systems,aqueous medium is active,air stable,recyclable,and involving no expensive and enviro-nmentally unfavorable phosphine ligand.
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Keywords:
- chalcone,
- vinylboronic acid,
- ionic liquid(IL),
- water,
- cross-coupling reaction
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