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Citation: Fan Baochen, Lin Yonghua, Shen Qi. SYNTHESES,STRUCTURES AND PROPERTIES OF η⁶-ARENE ORGANOLANTHANOIDS Ⅲ.SYNTHESIS OF RE(C₆H₆)(AlCl₄)₃C₆H₆(RE=La,Nd) AND THE MOLECULAR STRUCTURE OF Nd(C₆H₆)(AlCl₄)₃C₆H₆[J]. Chinese Journal of Applied Chemistry, ;1990, 7(6): 23-27. shu

SYNTHESES,STRUCTURES AND PROPERTIES OF η⁶-ARENE ORGANOLANTHANOIDS Ⅲ.SYNTHESIS OF RE(C₆H₆)(AlCl₄)₃C₆H₆(RE=La,Nd) AND THE MOLECULAR STRUCTURE OF Nd(C₆H₆)(AlCl₄)₃C₆H₆

1.
Laboratory of Rare-earth Chemistry and Physics Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Received Date: 30 November 1989
Available Online: 20 April 1990
Fund Project:

AlCl₃ which was activated by heating with aluminum powder reacts with RECl₃ in benzene solution giving two new neutral arene complexes, RE(C₆H₆) (AlCl₄)₃C₆H₆ (RE=La, Nd).The complexes were characterized by elemental analysis and IR spectra measurement. The molecular structure of necdium containing complex has been determined. It's isomor-phous and isostructural with Sm(C₆H₆) (AlCl₄)₃C₆H₆. The Nd-C and Nd-Cl bond lengths are respectively longer than Sm-C and Sm-Cl bond lengths in corresponding Sm-containingcomplex.
- light lanthanoids,
- neutral arene complex,
- synthesis,
- structure
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SYNTHESES,STRUCTURES AND PROPERTIES OF η6-ARENE ORGANOLANTHANOIDS Ⅲ.SYNTHESIS OF RE(C6H6)(AlCl4)3C6H6(RE=La,Nd) AND THE MOLECULAR STRUCTURE OF Nd(C6H6)(AlCl4)3C6H6

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SYNTHESES,STRUCTURES AND PROPERTIES OF η⁶-ARENE ORGANOLANTHANOIDS Ⅲ.SYNTHESIS OF RE(C₆H₆)(AlCl₄)₃C₆H₆(RE=La,Nd) AND THE MOLECULAR STRUCTURE OF Nd(C₆H₆)(AlCl₄)₃C₆H₆