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Citation: Fang Jingli, Wu Naijun, Wang Zhanwen. XPS AND AES STUDIES OF ANTITARNISH FILM ON TIN SURFACE[J]. Chinese Journal of Applied Chemistry, ;1990, 7(6): 9-13. shu

XPS AND AES STUDIES OF ANTITARNISH FILM ON TIN SURFACE

1.
1. Applied Chemistry Institute, Nanjing University, Nanjing 210008;
2.
2. Department of Applied Chemistry, Nanjing Institute of Chemical Technology, Nanjing

Received Date: 16 November 1989
Available Online: 7 April 1990

It is found by accelerating tarnish test of cysteine solution that ethylenediamine tetra-methylene phosphoric acid (EDTMP) was an excellent antitarnishing agent for tinplate. The antitarnish mechanism of EDTMP for tinplate has been studied by XPS, AES and laser Raman spectromety. A complicated anticorrosion film was formed on tin surface. The rela-tive atomic percent contents (A. C.%) or the film obtained from the constant element como-sition region of the profile curves were O 48.0%,Sn 10.7%, N7.7%,C 23.1% and P10.5.
- XPS,
- AES,
- antitarnish film,
- tin
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