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Citation: Meng Jian, Zeng Zuotao, Ren Yufang. THE STRUCTRUE AND ELECTRIC PROPERTY OF Sr₃Cu₅O_8+x AND CaSrCu₃O_5+x[J]. Chinese Journal of Applied Chemistry, ;1990, 7(4): 86-89. shu

THE STRUCTRUE AND ELECTRIC PROPERTY OF Sr₃Cu₅O_8+x AND CaSrCu₃O_5+x

1.
Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Received Date: 20 September 1989
Available Online: 18 December 1989
Fund Project:

The compounds with the compositions of Sr₃Cu₅O_8+x and CaSrCu₃O_5+x have been syn-thesized by solid phase reaction method. The crystal structures of both compounds are or-thorhombic with a=3.950Å, b=11.479Å and c=13.420Å for Sr₃Cu₅O_8+x and a=6.489Å,b=11.280Å and c=12.240Å for CaSrCu₃O_5+x, respectively. The oxygen content and oxida-ation state of copper ion were analysized by the iodometric titration. The electric property measurement indicates that both compounds are p-type semiconductor and have lower resis-tivity. They decomposes at around 936℃.
- Sr₃Cu₅O_8+x,
- CaSrCu₃O_5+x,
- structure,
- electric property
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THE STRUCTRUE AND ELECTRIC PROPERTY OF Sr₃Cu₅O_8+x AND CaSrCu₃O_5+x