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Citation: Ye Weizhen, Xu Qingren, Sun Guiun, Wu Fubing, Jiang Yatong. STUDIES ON HIGHLY STERICALLY HINDERED ORGANOPHOSPHORUS EXTRACTANTS Ⅰ.SYNTHESIS OF MONOHEXADECYL HYDROCARBYLPHOSPHONATES AND THEIR EXTRACTION BEHAVIOURS ON Co(Ⅱ),Ni(Ⅱ)AND OTHER METAL IONS[J]. Chinese Journal of Applied Chemistry, ;1990, 7(4): 1-5. shu

STUDIES ON HIGHLY STERICALLY HINDERED ORGANOPHOSPHORUS EXTRACTANTS Ⅰ.SYNTHESIS OF MONOHEXADECYL HYDROCARBYLPHOSPHONATES AND THEIR EXTRACTION BEHAVIOURS ON Co(Ⅱ),Ni(Ⅱ)AND OTHER METAL IONS

1.
Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai 200032

Received Date: 14 August 1989
Available Online: 16 February 1990
Fund Project:

Six monohexadecyl hydrocarbylphosphonate extractants with highly steric hindrance,R¹ (R²O) P(O) OH, where R² represents-CH (C₆H₁₃) C₂H₄CH(C₂H₅) C₄H₉ or -CHC₆H₁₃)CH₂CH (CH₃)C₆H₁₃), as well as R¹ represents CH₃, C₂H₅, i-C₃H₇, cyclo-C₆H₁₁ and C₆H₅, respe-ctively, were synthesized and their extraction behaviours on Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ), Fe(Ⅲ) and Ca were investigated. The structural variation of the hydrocarbyl groups in the extrac-tant molecules has the different influences on the extractability of various metal ions.The compounds with isopropyl and cyclohexyl, having higher steric hindrance, possess higher separation ability of Co and Ni, and they are a new class of extractants superior to mono-2-ethylhexyl 2-ethylhexyl phosphonate (P-507), which has already been employed in industry.
- monohexadecyl hydrocarbylphosphonate,
- NI(Ⅱ),
- Co(Ⅱ),
- extraction,
- organophosphorus compound
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