Citation:
Tao Yi, Zeng Guorong. PREPARATION AND CATALYTIC ACTIVITY OF POLYSTYRENE SUPPORTED PHOSPHONIUM SALTS[J]. Chinese Journal of Applied Chemistry,
;1990, 7(3): 69-71.
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A series of polystyrene supported phosphonium salts with degree of functionality of 0.36~0.62mmol/g were prepared by reacting bromoalkylated resins with tributylphosphine. The activity of these catalysts were examined by nucleophilic substitution reactions, such as cyanidation, iodization, and sultide formation. They showed satisfactory catalytic efficiency.
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Keywords:
- triphase catalyst,
- phosphonium,
- phase-transfer catalyst
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