Citation:
Song Yongxian, Peng Xinsheng, Li Rongxian. STUDY ON THE LATENT ACCELERATOR FOR EPOXY RESIN Ⅱ.EFFECT OF THE ACCELERATOR ON PHYSICAL PROPERTIES OF CURED RESIN[J]. Chinese Journal of Applied Chemistry,
;1990, 7(3): 29-32.
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The effect of a novel latent accelerator, neodymium acetylacetonate(AD), on the proper-ties of cured resin for bisphenol A epoxy resin(E-44)/Tung oil acid anhydride(TOA) system is reported in this paper. Presence of AD decreased the gel time at 150℃ and increased the activation energy with increasing amount of AD. The E-44/TOA/AD system displayed bet-ter storage stability at 40℃ than the control. The incorporation of AD into the epoxy resin caused an increase in the Tg values and depressed the dielectric loss Tanδ at 130℃.155℃ of Nd ion-containing epoxy. The mechan-ical properties were raised as compared with the control. It might be due to the special electron structure of rare-earth elements which makes the epoxy system having higher Tg owing to the higher crosslink density or more homogenoous network structure.
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Keywords:
- epoxy resin,
- latent accelerator,
- physical property
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