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Citation: Yuan Jinhua, Xin Feibo, Xin Xinquan, Dai Anbang. SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅪ THERMAL DECOMPOSITION OF K₃(Co(CN)₅L)[J]. Chinese Journal of Applied Chemistry, ;1990, 7(2): 65-68. shu

SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅪ THERMAL DECOMPOSITION OF K₃(Co(CN)₅L)

1.
Coordination Chemistry Institute, Nanjing University, Nanjing 210008

Received Date: 30 November 1988
Available Online: 23 August 1989
Fund Project:

Thermal decomposition of the title compounds (L=NO^-, CN^-, NO₂^-, N₃^-) in helium and vacuum has been studied by gas chromatography and quadrupole mass spectrometry. The result shows that the substitute ligand released prior to cyano group and the order of the decomposition temperature of substituted ligands is NO^- < N₃^- < NO₂^- < CN^-. Appearance of potassiun cyanocobaltate(Ⅲ) in decomposition products shows a rearlan-gement occured among solid. compounds during the decomposition reaction.
- solid reaction,
- coordination chemistry,
- cobaltic pentacyanide complex,
- thermal decomposition
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SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅪ THERMAL DECOMPOSITION OF K3(Co(CN)5L)

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SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅪ THERMAL DECOMPOSITION OF K₃(Co(CN)₅L)