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Citation: Tong Yuejin, Ding Mengxian. ASYMMETRIC SYNTHESIS OF AROMATIC CYANOHYDRINS CATALYSED BY CYCLO(L-Phe-L-His)[J]. Chinese Journal of Applied Chemistry, ;1990, 7(1): 23-27. shu

ASYMMETRIC SYNTHESIS OF AROMATIC CYANOHYDRINS CATALYSED BY CYCLO(L-Phe-L-His)

1.
Changchun Institute of Applied Chemistry Academia Sinica Changchun 130022

Received Date: 18 April 1989
Available Online: 29 July 1989

Cyclo(L-Phe-L-His) prepared by a modified procedure showed high activity. and enan-tioselectivity in the asymmetric synthesis of aromatic Cyanohydrins from benzaldehyde and m-phenoxybenzaldehyde. The influence of the reaction conditions on the activity and sele-ctivity of the dipeptide has been investigated. The cyclodipeptide can be easily recovered and reused without any loss of the catalytic activity. The optical and chemical stability as well as the relationship between the aggregation and properties of the catalyst have been discussed.
- optically active cyanohydrin,
- cyclic dipeptide,
- asymmetric synthesis
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