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Citation: Jin Yingtai, Lin Yonghua, Jin Songchun, Hu Gang, Li Zhenxiang, Zhang Xitian. SYNTHESIS AND CRYSTAL STRUCTURE OF BIMETALLIC YTTRIUM COMPLEX[J]. Chinese Journal of Applied Chemistry, ;1989, 6(6): 67-70. shu

SYNTHESIS AND CRYSTAL STRUCTURE OF BIMETALLIC YTTRIUM COMPLEX

1.
The Laboratory of Chemistry and Physics of Rare Earth, Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 30 December 1988
Available Online: 7 June 1989

The synthesis and growth of crystal of a new bimetallic yttrium complex are presented in this is paper. The crystal structure of the complex, [(CF₃CO₂)₃YA1(C₂H-5)₂·2THF]₂, was determined by a four circlc diffractometer. The erystals belong to monoclinic system with space group P2_1/n,a=10.173 Å,b=18.713 Å,c=14.704 Å,β=102.318°,V=2734.43 Å.Least square refinement has led to a final R of 0.070,R_w=0.064. The Y-O(PF₃CO₂)(THF) average distance 2.323(2.451) Å. The Al-O(CF₃CO₂) and Al-C(C₂H₅) distances average 1.840,1.998 Å respectively. The valence state of the yttrium is discussed based on the data of ¹H-NMR and ESCA results. The Y-Y bond length indicated that the complex likely belongs to a cluster compound.
- Bimetallic rare earth complex,
- Yttrium complex,
- Crystal structure,
- Valence state of yttrium,
- Cluster complex
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