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Citation: Wang Xianyuan, Zhang Jian, Li Guangnian. SYNTHESES OF ms-TETRA(ALKYLTHIOPHENYL)PORPHYRINS AND THEIR METAL COMPLEXES[J]. Chinese Journal of Applied Chemistry, ;1989, 6(6): 58-60. shu

SYNTHESES OF ms-TETRA(ALKYLTHIOPHENYL)PORPHYRINS AND THEIR METAL COMPLEXES

1.
Chengdu Institute of Organic Chemistry, Academia Sinica

Received Date: 28 October 1988
Available Online: 4 July 1989

ms-Tetra (p-alkylthiophenyl) porphyrins and ms-tetra (o-alkylthiophenyl) porphyrins (alkyl=methyl, ethyl, propyl) were synthesized by refluxing the mixture of pyrrole and para or ortho (alkylthio) benzaldehydes in propionic acid or in acetic acid. Some metal complexes of these porphyrins were prepated by refluxing the mixture of the porphyrin and the corresponding metal salt in acetic acid or in DMF. All the porphyrins described were identified by visible spectrophotometry, nuclear magnetic resonance spectroscopy and elemental analysis.
- ms-Tetra(alkylthiophenyl)porphyrin,
- Metalloporphyrin,
- Complex Synthesis,
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