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Hou Shifa, Wang Wenyun. KINETIC STUDY ON THE Zn(Ⅱ)-HEMATOPORPHYRIN INCORPORATION REACTION IN MICELLAR MEDIUM[J]. Chinese Journal of Applied Chemistry,
;1989, 6(6): 44-47.
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The kinetic behavior of Zn(Ⅱ)-hematoporphyrin formation reaction in anionic and nonionic surfactant mediums has been studied by the two-exponential fitting of fluorescence decay time of the system. The metal-porphyrin intexaction mechanism and the incorporation rate equations have been suggested.The similar study of Zn(Ⅱ)-tetraphenylporphyrin system was carried out to check tbe validity of the time-resolved fluorescence approach proposed by the authors.
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