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Citation: Jin Zhongsheng, Nie Guojun, Hu Ninghai, Chen Wenqi. CRYSTAL STRUCTURE OF SmCl₃(DME)·2THF[J]. Chinese Journal of Applied Chemistry, ;1989, 6(3): 68-70. shu

CRYSTAL STRUCTURE OF SmCl₃(DME)·2THF

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 19 November 1988
Available Online: 20 May 1988

The crystal structure of the title compound in which DME=Dimethoxyethane was determined using x-ray diffractometer. The complex crystallizes in monoclinic space group P2₁/_a with Z=4. Lattice parameters are: a=13.547(8), b=8.607(4), c=16.029(9)Å,β=90.35(5)°. The crystal structure was determined by Patterson and Fourier techniques and refined by least-squares to a final value R=0.0443. The samarium(Ⅲ) ion is 7-coordinate,being bonded to three chlorine atoms, two oxygen atoms of two THF and two oxygen atems of DME. The Sm-Cl distances are in the range 2.647-2.674Å. The Sm-O distances are in the range 2.465-2.504Å.
- Complex of samarium with dimethoxyethane,
- Crystal structure,
- x-Ray
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CRYSTAL STRUCTURE OF SmCl3(DME)·2THF

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CRYSTAL STRUCTURE OF SmCl₃(DME)·2THF