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Citation: Li Chaojun, Li Jisheng, Chen Deheng. A NEW METHOD FOR SYNTHESIS OF β, γ-UNSATURATED AMIDES[J]. Chinese Journal of Applied Chemistry, ;1989, 6(3): 57-58. shu

A NEW METHOD FOR SYNTHESIS OF β, γ-UNSATURATED AMIDES

1.
1. Institute of Chemistry, Academia Sinica, Beijing;
2.
2. Department of Chemistry, McGill University, Canada

Received Date: 13 July 1988
Available Online: 14 October 1988

Reaction of vinylalanate obtained from the readily available. dialkylvinylalane and n-butyl lithium with α-halo-amides produced the corresponding 6, γ-unsaturated amides, withclean retention of the configuration. The yields were 35% to 70%.
- Unsaturated amide,
- Vinylalane,
- Synthesis,
- Ate-complex
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