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Citation: Wang Yuling, Chen Wenqi, Zhang Bin. SYTHESES OF CYCLOPENTANYL(OR ALLYL)CYCLOPENTA-DIENYL LATHANOID DIOHLORIDE TETRAHYDROFURANATE COMPLEXES[J]. Chinese Journal of Applied Chemistry, ;1989, 6(3): 37-41. shu

SYTHESES OF CYCLOPENTANYL(OR ALLYL)CYCLOPENTA-DIENYL LATHANOID DIOHLORIDE TETRAHYDROFURANATE COMPLEXES

1.
1. Changchun Institute of Applied Chemistry, Academia Sinica;
2.
2. Department of Chemistry, Heilongjiang University, Harbin

Received Date: 23 July 1988
Available Online: 20 October 1988

In this paper the syntheses of cyclopentanyl (ora llyl) cyclopentadienyl lanthanoid dichloride tetrahydrofuranate complexes are first reported. The complexes of C₅H₉C₅H₄·LnCl₂-nTHF and C₃H₅C₅H₄LnCl₂·nTHF (C₃H₉C₅H₄=cyclopentanyl cyclopentadienyl; C₃H₅C₅H₄=allylcyclopentadienyl; Ln=Nd, Sm, Gd; n=0, 1, 2, 3) are identified by elemental analysis, thermal analysis, IR, MS and NMR measurements. The crysal structure of the reaction intermediate C₅H₉C₅H₄Na·THF was determined by the x-ray diffraction method.
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