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Citation: Yuan Yaofeng, Li Fengze. REDUCTION OF ACYL DERIVATIVES OF 2, 2-BIS-FERROCENYLALKANES[J]. Chinese Journal of Applied Chemistry, ;1989, 6(3): 15-20. shu

REDUCTION OF ACYL DERIVATIVES OF 2, 2-BIS-FERROCENYLALKANES

Yuan Yaofeng ,
Li Fengze

1.
Department of Chemistry, Inner Mongolia University, Huhehote

Received Date: 18 July 1988
Available Online: 8 November 1988

A series of acyl derivatives of 2,2-bis-ferrocenylalkanes have been prepared from 2,2-bis-lerrocenylakanes (i.e. bisferrocenyl methane, 2, 2-bisferrocenylpropane, 2, 2-bis-ferrocenylbutane and 2, 2-bisferrocenylpentane) and acid anhydrides (i.e.acetic-propionic-,n-butyric anhydride) by Friedel-Crafts acylation. The ketones were reduced to the corresponding α-hydroxyalkyl derivatives of 2, 2-bisferrocenylalkanes with LiAlH₄·Eighteen α-hydroxyalkyl and di-(α-hydroxyalkyl)derivatives have been synthesized. The synthesis and characteristies of IR and ¹HNMR spectra of the compounds have been discussed.
- Bisferrocenyl methane,
- 2,2-Bisferrocenyl propane,
- 2,2-Bisferrocenyl butane,
- 2,2-Bisferrocenyl pentane,
- Friedel-Crafes acylation reaction,
- α-hydroxyalkyl derivetivs
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