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Citation: Nie Guojun, Hu Ninghai, Jin Zhongsheng, Chen Wenqi. SYNTHESES OF BINUCLEAR COMPLEXES [C₅H₅Fe(CO)₂]-LnCl₂·nTHF AND [C₅H₅Fe(CO)₂][C₅H₄(SiMe₃)]LnCl·nTHF[J]. Chinese Journal of Applied Chemistry, ;1989, 6(2): 5-10. shu

SYNTHESES OF BINUCLEAR COMPLEXES [C₅H₅Fe(CO)₂]-LnCl₂·nTHF AND [C₅H₅Fe(CO)₂][C₅H₄(SiMe₃)]LnCl·nTHF

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 4 November 1987
Available Online: 18 August 1988

In this paper the preparation of the binuclear complexes [C₅H₅Fe(CO)₂]LnCl₂·nTHF (Ln=Nd, Sm, Gd; n=1,2) and [C₅H₅Fe(CO)₂][C₅H₄(SiMe₃)]LnCl·nTHF (Ln=Nd, Sm,Gd; n=0,1,3) is reported. Both complexes were identified by clemental analyses, thermal gravimetric analyses, infrared spectra, mass spectra, NMR and EPR. The infrared spectral data reveal the bridging carbonyls between the iron and the rare earth elements.[C₅H₅Fe(CO)₂]₂Na·4THF as a reaction intermediate in the preparation of [C₅H₅Fe-(CO)₂]LnCl₂nTHF was characterized by crystal structural analyses.
- Binuclear complex,
- Cyclopentadienyldicarbonyliron sodium,
- Trimethylsilylcyclopentadiene,
- Synthesis
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SYNTHESES OF BINUCLEAR COMPLEXES [C5H5Fe(CO)2]-LnCl2·nTHF AND [C5H5Fe(CO)2][C5H4(SiMe3)]LnCl·nTHF

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SYNTHESES OF BINUCLEAR COMPLEXES [C₅H₅Fe(CO)₂]-LnCl₂·nTHF AND [C₅H₅Fe(CO)₂][C₅H₄(SiMe₃)]LnCl·nTHF