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Chen Yuanyin, Feng Minhua. SYNTHESES AND PROPERTIES OF NETWORK POLYMERIC CROWN ETHERS Ⅰ. FROM BISGLYCIDYL ETHER,ETHYLENE GLYCOL BISGLYCIDYL ETHER OR DI(OR TRI, TETRA) ETHYLENE GLYCOL BISGLYCIDYL ETHER[J]. Chinese Journal of Applied Chemistry,
;1986, 3(5): 28-33.
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The synthetic method and properties of a series of new network polymeric crown ethers were reported in this paper. Eight network polymeric crown ethers were prepared by the net-polymerization of bisglycidyl ether, ethylene glycol bisglycidyl ether, diethylene glycol bisglycidyl ether triethylene glycol bisglycidyl ether and tetraethylene glycol bisglycidyle ther in the presence of BF3·OEt2 or (i-Bu)3Al as catalyst. The studied network polymeric crown ethers have good cation-complexing ability and effective catalytic activity in the nucleophilic substitution of PhOK with n-BuBr.
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