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Citation: K. M. Kadish, Wang Erkang. THE ELECTROCHEMISTRY OF METALLOPORPHYRINS IN NONAQUEOUS MEDIA[J]. Chinese Journal of Applied Chemistry, ;1986, 3(3): 1-7. shu

THE ELECTROCHEMISTRY OF METALLOPORPHYRINS IN NONAQUEOUS MEDIA

K. M. Kadish ¹ ,
Wang Erkang ²

1.
1. Department of Chemistry, University of Houston, U. S. A.;
2.
2. Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 30 September 1985
Available Online: 9 January 1986

In this review the emphasis will be placed on the electrochemical reactivity of synthetic metalloporphyrin complex in nonaqueous media. This review will summarize mechanistic data associated with the oxidation and reduction of metalloporphyrin and attempt to show the correlation of halfwave potentials (E_1/2) and electron transfer path ways with some factors such as substituent effect, axial-ligand coordination with nitrogeneous bases, with halide anions and with diatomic molecules; specific structure of the porphyrin ring system; basicity of the porphyrin ring; hydrogen ionbonding with the solvent etc.
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