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Citation: Hong Huahua, Wang Rou, Wang Xianyuan, Lu Quanjie, Li Guangnian. THE CATALYTIC BEHAVIORS OF AXIAL COORDINATED COMPLEXES OF IRON(Ⅲ) PORPHYRINS IN THE OXIDATION REACTION OF CYCLOHEXANE[J]. Chinese Journal of Applied Chemistry, ;1986, 3(2): 64-66. shu

THE CATALYTIC BEHAVIORS OF AXIAL COORDINATED COMPLEXES OF IRON(Ⅲ) PORPHYRINS IN THE OXIDATION REACTION OF CYCLOHEXANE

1.
Chengdu Institute of Organic Chemistry, Academia Sinica

Received Date: 4 March 1985
Available Online: 21 October 1985

The catalytic activities of iron(Ⅲ) porphyrins with an axially ligated imidazole(Im),2-methylimidazole (MeIm), pyridine (Py), or 4-methylpyridine (MePy), for the selective oxidation of cyclohexane in the model system have been investigated. It has been found that with imidazole ligand, a strong donor, the catalytic activity of iron porphyrin is slightly higher than that of hemin. The catalytic activities of the complexes derease in the order of Hemin·Im≈Hemin·MeIm >Hemin·Py≈Hemin·MePy≈Hemin>ClFe (Ⅲ)TPP·Im >ClFe (Ⅲ) TPP.
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